PHENYLALLYLCHLORO-[1,3-BIS(DIISOPROPYLPHENYL)-2-IMIDAZOLIDINYLIDENE]PALLADIUM(II) - Names and Identifiers
Name | Palladium,[1,3-bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]chloro[(1,2,3-h)-3-phenyl-2-propenyl]-,stereoisomer
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Synonyms | PHENYLALLYLCHLORO-[1,3-BIS(DIISOPROPYLPHENYL)-2-IMIDAZOLIDINYLIDENE]PALLADIUM(II) Phenylallylchloro-[1,3-Bis(Diisopropylphenyl)-2-Imidazolidinylidene]Palladium(Ii) Chloro[(1,2,3-Η)-3-Phenyl-2-Propenyl][1,3-Bis(2,6-Di-I-Propylphenyl)-4,5-Dihydroimidazol-2-Ylidene]Palladium(Ii) Chloro[(1,2,3-N)-3-Phenyl-2-Propenyl][1,3-Bis(2,6-Di-I-Propylphenyl)-4,5-Dihydroimidazol-2-Ylidene]Palladium(Ii) CHLORO[(1,2,3-Η)-3-PHENYL-2-PROPENYL][1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE]PALLADIUM(II) Chloro[(1,2,3-Η)-3-Phenyl-2-Propenyl][1,3-Bis(2,6-Di-I-Propylphenyl)-4,5-Dihydroimidazol-2-Ylidene]Palladium(II) Palladium,[1,3-bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]chloro[(1,2,3-h)-3-phenyl-2-propenyl]-,stereoisomer Palladium, [1,3-bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]chloro[(1,2,3-η)-1-phenyl-2-propen-1-yl]-, stereoisomer
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CAS | 884879-24-7
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PHENYLALLYLCHLORO-[1,3-BIS(DIISOPROPYLPHENYL)-2-IMIDAZOLIDINYLIDENE]PALLADIUM(II) - Physico-chemical Properties
Molecular Formula | NeolystCX32
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Molar Mass | 649.64 |
Melting Point | 0°C |
Boling Point | 0°C |
Flash Point | 0°C |
Storage Condition | 2-8℃ |
PHENYLALLYLCHLORO-[1,3-BIS(DIISOPROPYLPHENYL)-2-IMIDAZOLIDINYLIDENE]PALLADIUM(II) - Risk and Safety
Hazard Symbols | Xi - Irritant
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Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin.
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Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37 - Wear suitable protective clothing and gloves.
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WGK Germany | 3 |
HS Code | 28439000 |
PHENYLALLYLCHLORO-[1,3-BIS(DIISOPROPYLPHENYL)-2-IMIDAZOLIDINYLIDENE]PALLADIUM(II) - Introduction
This compound is the normal isomer of [PdCl([1,3-bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene])][3-phenylallyl]. Some of its main properties and applications are as follows:
Nature:
-Molecular formula: C39H43ClN2Pd
-Molecular weight: 671.48g/mol
-Appearance: White crystalline powder
-Melting Point: 204-207°C
-Solubility: Soluble in a variety of organic solvents such as chloroform, toluene
Application:
-This compound is a commonly used ligand that can be used to assist in catalyzing a variety of organic synthesis reactions, such as cross-coupling reactions, carbon-nitrogen bond formation reactions, etc.
-In the field of organic synthesis, it can be used as a palladium-catalyzed adsorbent and catalyst, and can be applied to substrate activation, selective catalytic reactions, etc.
Preparation Method:
The synthesis of the compound is more complex, including multiple steps of organic synthesis reaction. For example, the compound can be synthesized by performing a nucleophilic substitution reaction and a complexing reaction under appropriate conditions using the relevant ligand and PdCl2(CH3CN)2 as starting materials.
Safety Information:
There is limited safety information regarding the normal isomer of [PdCl([1,3-bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene])][3-phenylallyl]. When handling and handling, it is necessary to follow the basic safety practices of the chemical laboratory, such as wearing appropriate personal protective equipment (such as gloves, glasses, etc.) to avoid inhalation or contact with the compound. In addition, it must be stored in a dry, well-ventilated place.
Last Update:2024-04-10 22:29:15